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51.
采用高效液相色谱法结合一测多评法测定了隔山消发酵前后2,4-二羟基苯乙酮、2,5-二羟基苯乙酮和白首乌二苯酮等3种苯乙酮类化合物的含量。分别制备发酵前后的隔山消样品溶液,色谱分析中采用Thermo C18色谱柱作为固定相,用不同比例的水(A)、乙腈(B)和甲醇(C)的混合液作为流动相进行梯度洗脱,达到上述3种组分的良好分离。采用二极管阵列检测器在相同的检测波长(265nm处)分别测定3种组分的峰面积。分别用一测多评法(QAMS)和外标法计算所测定组分的含量,结果表明两种计算方法所得结果相似性极高,据此认为在隔山消发酵前后的样品溶液中各组分的质量评价中采用QAMS是可行的。按上述方法分析了同一批隔山消样品12份,取其中6份经发酵处理,对所得结果的平均值进行了比较,未经发酵的样品溶液中2,4-二羟基苯乙酮的质量分数为0.208mg·g^-1、2,5-二羟基苯乙酮的质量分数为0.152mg·g^-1,与经发酵的样品溶液中的质量分数(2,4-二羟基苯乙酮的质量分数为0.235mg·g^-1、2,5-二羟基苯乙酮的质量分数为0.180mg·g^-1)相比呈升高趋势,而白首乌二苯酮的质量分数由未经发酵样品溶液中的0.678mg·g^-1下降为发酵样品溶液中的0.543mg·g^-1。此外,研究结果还表明,不同含量的2,5-二羟基苯乙酮和白首乌二苯酮相对于2,4-二羟基苯乙酮(参照物)的相对校正因子和相对保留时间基本相同。 相似文献
52.
Yan‐mei Shi Lin Mei Jun‐xia Zhang Kai Hu Xi Zhang Zhu‐zhu Li Ming‐san Miao Xiu‐min Li 《Electroanalysis》2020,32(7):1507-1515
A new electrochemical sensor material has been fabricated via the non‐covalent functionalization of reduced graphene oxide (rGO) and soluble tetramino zincphthalocyanines (ZnPc‐NH2). Immobilization of uricase onto the synthesized nanohybrids can evidently improve the electrocatalytic activity and selectivity. The obtained composite membrane possesses a great enhancement of electron transfer rate and excellent synergistic electrocatalytic effect toward uric acid (UA) oxidation under the working potential at 0.620 V vs. Ag/AgCl with a scan rate of 0.125 V/s. The effects of the experimental parameters on the electrochemical oxidation responses of UA were investigated and optimized in detail. Under the optimized conditions, the peak currents were proportional to the UA concentration in a range from 0.5 to 100 μmol/L with detection limit of 0.15 μmol/L. Moreover, the developed sensor was applied for UA determination in human urine samples with high accuracy and satisfactory recovery, which is envisioned to have promising applications in monitoring UA in clinical research. 相似文献
53.
Let M and N be nonzero subspaces of a Hilbert space H, and PM and PN denote the orthogonal projections on M and N, respectively. In this note, an exact representation of the angle and the minimum gap of M and N is obtained. In addition, we study relations between the angle, the minimum gap of two subspaces M and N, and the reduced minimum modulus of (I - PN)PM, 相似文献
54.
This paper considers such a group G which possesses nontrivial proper subgroups H 1 ,H 2 such that any proper subgroup of G not contained in H 1 ∪ H 2 is p-closed and obtains that if G is soluble,then the number of prime divisors contained in |G| is 2,3 or 4;if not,then it has a form x N where N/Φ(N) is a non-abelian simple group.Then the structure of such a group is determined for p = 2,H 1 = H 2 under some conditions. 相似文献
55.
Non-uniformity correction is the key issue for the image quality improvement of infrared focal panel array (IRFPA) imaging. A non-uniformity correction (NUC) algorithm for IRFPA based on motion controllable micro-scanning platform and perimeter diaphragm strips is presented. We initially execute one-point calibration to the perimeter detectors, then based on controllable motion of adjacent frames, a special algebraic algorithm is proposed to transport the calibration of the perimeter detectors to those interior un-corrected ones. In this way, the bias parameter of the whole field of view (FOV) is calculated. The algorithm can be easily combined with sub-pixel imaging, thereby improving the quality of thermal imaging system (image spatial resolution and uniformity). All calculations are algebraic, with a low computation load. The algorithm can realize adaptive one point calibration without covering the central FOV rapidly. Experiments on simulated infrared data demonstrate that this algorithm requires only dozens of frames to obtain high quality corrections. 相似文献
56.
Yuguo Li Ruiqin Peng Xianwu Xiu Xuelei Zheng Xiaosen Zhang Guannan Zhai 《Superlattices and Microstructures》2011,50(5):511-516
Tin oxide (SnO2) nanoparticles were fabricated by evaporation of Sn powers at 1000 °C in air pressure. The as-deposited SnO2 particles were single crystal structure, which were mostly spherical shape, the diameter of particles was ranging from 200 to 600 nm. The photoluminescence (PL) spectrum showed that a sharp emission peak at around 393 nm with the excitation wavelength at 325 nm, which suggested possible applications in nanoscaled optoelectronic devices. It was also found that the holding time affects the morphology of the products. The formation mechanism of SnO2 particles was discussed. 相似文献
57.
58.
Tailoring 3,3′‐Dihydroxyisorenieratene to Hydroxystilbene: Finding a Resveratrol Analogue with Increased Antiproliferation Activity and Cell Selectivity 下载免费PDF全文
Yan‐Fei Kang Wen‐Jing Yan Ting‐Wen Zhou Dr. Fang Dai Dr. Xiu‐Zhuang Li Xia‐Zhen Bao Yu‐Ting Du Cui‐Hong Yuan Hai‐Bo Wang Xiao‐Rong Ren Dr. Qiang Liu Dr. Xiao‐Ling Jin Prof. Dr. Bo Zhou Prof. Dr. Jie Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(29):8904-8908
Four novel compounds were designed by “tailoring” 3,3′‐dihydroxyisorenieratene (a natural carotenoid) based on an isoprene unit retention truncation strategy. Among them, the smallest molecule 1 (2,3,6,2′,3′,6′‐hexamethyl‐4,4′‐dihydroxy‐trans‐stilbene) was concisely synthesized in a one‐pot Stille–Heck tandem sequence, and surfaced as a promising lead molecule in terms of its selective antiproliferative activity mediated by blocking the NCI‐H460 cell cycle in G1 phase. Additionally, theoretical calculations and cell uptake experiments indicate that the unique polymethylation pattern of compound 1 significantly induces a conformational change shift out of planarity and increases its cell uptake and metabolic stability. The observation should be helpful to rationally design resveratrol‐inspired antiproliferative agents. 相似文献
59.
Inside Cover: Uniaxial Movements of a Metal–Cyanide Framework Switched by Weak Interactions through Dehydration and Rehydration (Chem. Eur. J. 27/2014) 下载免费PDF全文
60.
Enhua Wang Suwen Liu Qifang Lu Zhiliang Xiu Tanggang Li Lingjun Song 《Journal of Sol-Gel Science and Technology》2011,58(3):705-710
A novel plasmonic photocatalyst, i.e., acid-etched TiO2 nanobelts attached with Ag/AgI nanoparticles (NPs) was prepared by deposition–precipitation-photoreduction method. Such surface-modified nanobelts had larger area than the normal one. Ag NPs were formed from AgI by photo-reduction under Xenon lamp irradiation. X-ray diffraction, scanning electron microscopy analysis, UV–Vis diffuse reflectance spectra and fluorescence spectra were used to characterize the structure and optical properties of the sample. The obtained sample exhibited strong photodegradation of methyl orange (MO) under visible light irradiation, which were attributed to both the surface plasmon resonance of Ag NPs and the visible light actived AgI. The photodegradation was accomplished by the transfer of photoexcited electrons from the Ag NPs to the acid-etched TiO2 nanobelts. After four cycles of photodegradation the photocatalyst was still stable. This novel photocatalyst had a high potential application in wastewater-treatment and biomedical engineering. 相似文献